1: poly[methyl(2-phenylethenyl)siloxane] With potassium carbonate in toluene T=20°C; 1 h; 2: 1-chloro-4-nitro-benzene With [(P{(C6H11)3})2Pd(Cl)2] in toluene T=120°C;
sodium acetate; [cis-CH2{NCH=CHN(4-CH2=CHBn)C}2PdCl2] in N,N-dimethyl acetamide T=150°C; Heck coupling; 42 h; Title compound not separated from byproducts.;
参考文献
Scherg, Tobias; Schneider, Sabine K.; Frey, Guido D.; Schwarz, Juergen; Herdtweck, Eberhardt; Herrmann, Wolfgang A.
Synlett, 2006 , # 18 p. 2894 - 2907
