1.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; InI / tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide / 0 - 22 °C / |Inert atmosphere 2.1: trifluoroacetic acid / 48 h / |Inert atmosphere 3.1: 2,2,6,6-tetramethylpiperidinyl-lithium / tetrahydrofuran / 0.5 h / -78 °C / |Inert atmosphere 3.2: 6.5 h / -78 - 0 °C / |Inert atmosphere 4.1: (Ipc)2BH / tetrahydrofuran / 0 °C / |Glovebox; |Inert atmosphere 4.2: 2 h / 0 °C / |Glovebox; |Inert atmosphere 4.3: 0 - 25 °C / |Glovebox; |Inert atmosphere 5.1: lithium hydroxide hydrate; water / methanol / 24 h / 45 °C / |Inert atmosphere 6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / water; dichloromethane / 0.17 h / 0 °C 7.1: chloroformic acid ethyl ester; triethylamine / dichloromethane / 2 h / 0 °C / |Inert atmosphere 7.2: 2.5 h / 0 - 25 °C / |Inert atmosphere 8.1: cesium fluoride; methanol / 3 h / 25 °C / |Inert atmosphere View Scheme

manganese; titanium tetrachloride in tetrahydrofuran T=-10°C; 0.666667 h; Inert atmosphere; optical yield given as percent de;

in ethanol 2 h; Ambient temperature;

TEA in N,N-dimethyl-formamide

potassium cyanide in dimethyl sulfoxide 0.133333 h; Inert atmosphereSonication;

potassium cyanide; ethanol

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manganese; titanium tetrachloride in tetrahydrofuran T=-10°C; 0.666667 h; Inert atmosphere; optical yield given as percent de;