4,4'-二硝基二苯二硫醚合成路线 （共 219 条）
反应条件
1: Cl2 / CHCl3 2: CHCl3 View Scheme
参考文献
Stepanov,B.I. et al.
Zhurnal Organicheskoi Khimii, 1977 , vol. 13, p. 370 - 374,334 - 338
反应条件
sulfur in ammonia T=60°C; 2 h; variation of temperature and amount of raegent; MechanismProduct distribution;
参考文献
Sato, Ryu; Chiba, Shuji; Saito, Nobushige; Sato, Mikiya; Saito, Minoru
Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 205 - 212
反应条件
potassium fluoride; bis(fluoroxy)methane T=-20 - -15°C;
参考文献
AIR PRODUCTS AND CHEMICALS, INC.
Patent: EP1484318 A1, 2004 ;
Location in patent: Page 10; 11 ;
反应条件
fluorine in acetonitrile T=-35 - -25°C;
参考文献
AIR PRODUCTS AND CHEMICALS, INC.
Patent: EP1484318 A1, 2004 ;
Location in patent: Page 12 ;
反应条件
1: Cl2 / CHCl3
2: CHCl3
View Scheme
参考文献
Stepanov,B.I. et al.
Zhurnal Organicheskoi Khimii, 1977 , vol. 13, p. 370 - 374,334 - 338
反应条件
sulfur in ammonia
T=20°C; 2 h; variation of temperature and amount of raegent; MechanismProduct distribution;
参考文献
Sato, Ryu; Chiba, Shuji; Saito, Nobushige; Sato, Mikiya; Saito, Minoru
Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 205 - 212
反应条件
tetrakis(triphenylphosphine) palladium(0); copper(I) thiophene-2-carboxylate; triethylamine in 1,4-dioxane
T=110°C; 24 h; Inert atmosphereSealed tubeSchlenk technique; chemoselective reaction;
参考文献
Quan, Zheng-Jun; Lv, Ying; Jing, Fu-Qiang; Jia, Xiao-Dong; Huo, Cong-De; Wang, Xi-Cun
Advanced Synthesis and Catalysis, 2014 , vol. 356, # 2-3 p. 325 - 332
反应条件
(i) SO2Cl2, AcOH, CH2Cl2, (ii) H2O; Multistep reaction;
参考文献
Buckman,J.D. et al.
Journal of Organic Chemistry, 1967 , vol. 32, p. 1626 - 1627
反应条件
potassium hydroxide; potassium chloride in isopropyl alcohol
T=25°C; various carbanions and disubstituted diaryl disulfides investigated; Rate constant;
参考文献
Gilbert, H. F.
Journal of the American Chemical Society, 1980 , vol. 102, # 23 p. 7059 - 7065
反应条件
1: 68 percent / Na2HPO4; HOCH2SO2Na / dimethylformamide; H2O / 2.5 h / 20 °C / 9000.9 Torr
2: 95 percent / trichloroisocyanuric acid; [Bmim]BF4; H2O / 3.5 h / 20 °C
3: 97 percent / iron; hydrochloric acid / H2O / 1 h / 90 °C
View Scheme
参考文献
Tang, Ri-Yuan; Zhong, Ping; Lin, Qiu-Lian
Journal of Fluorine Chemistry, 2007 , vol. 128, # 6 p. 636 - 640
