1: benzyl alcohol With 2,2,6,6-tetramethyl-piperidine-N-oxyl; [bis(acetoxy)iodo]benzene in dichloromethane 16 h; 2: 1-amino-2-propene With sodium tris(acetoxy)borohydride in dichloromethane chemoselective reaction;
1.1: oxalyl dichloride; Ph3PCl(+)Cl(-) / chloroform / 7 h / 20 °C 2.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 0 °C 2.2: 16 h / 20 °C View Scheme
参考文献
Denton, Ross M.; An, Jie; Adeniran, Beatrice; Blake, Alexander J.; Lewis, William; Poulton, Andrew M.
Journal of Organic Chemistry, 2011 , vol. 76, # 16 p. 6749 - 6767
