(S)-(+)-N-(3,5-dioxa-4-phosphacyclohepta-[2,1-a;3,4-a′]dinaphthalen-4-yl)dibenz[b,f]azepine; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; zinc(II) chloride in 1,2-dichloro-ethane
Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Roggen, Markus; Carreira, Erick M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 34 p. 8652 - 8655
potassium carbonate in N,N-dimethyl-formamide
T=20°C;
参考文献
Lin, Yuya A.; Chalker, Justin M.; Floyd, Nicola; Bernardes, Goncalo J. L.; Davis, Benjamin G.
Journal of the American Chemical Society, 2008 , vol. 130, # 30 p. 9642 - 9643