反应条件
1: phenyl-magnesium bromide With ZnCl2*TMEDA in tetrahydrofuran T=0°C; Negishi coupling reaction; Inert atmosphere; 2: N-(1-(4-bromophenyl)ethylidene)-4-methoxybenzenamine With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; 1,2-dichloro-2-methylpropane in tetrahydrofuran T=60°C; Negishi coupling reaction; 1.5 h; Inert atmosphere; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 3 h;
参考文献
Yoshikai, Naohiko; Matsumoto, Arimasa; Norinder, Jakob; Nakamura, Eiichi
Angewandte Chemie, International Edition, 2009 , vol. 48, # 16 p. 2925 - 2928
