in neat (no solvent) byproducts: hydrogen, pyrazol-1-ylpyrazaboles; a mixt. of PhNHMe and pyrazabole in 4:1 molar ratio was refluxed under Ar for 28 h; cooled to room temp., washed several times with toluene, residue was identified as N(NMePh)3 (NMR, IR, MS), the toluene washings were evapd., residue was shown to be a mixt. of pyrazol-1-ylpyrazaboles (primarily tetrakis substituted one) by NMR;
参考文献
Alam, Fazlul; Niedenzu, Kurt
Journal of Organometallic Chemistry, 1983 , vol. 243, # 1 p. 19 - 30
1: With acetic anhydride in acetonitrile T=0°C; 3 h; Molecular sieve; 2: With sodium tris(acetoxy)borohydride in acetonitrile T=0°C; 0.166667 h; Molecular sieve; Further stages;
Coyle, John D.; Newport, Graham L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 93 - 96
