sulfuric acid in 1,4-dioxane; water T=55°C; ΔH(excit.), ΔS(excit.), ΔG(excit.), kinetic solvent isotope kH/kD effect in the hydrolysis, substituent and temperature effect; Thermodynamic dataRate constantKinetics;
参考文献
Journal of Organic Chemistry, , vol. 59, # 6 p. 1369 - 1374
sulfuric acid in 1,4-dioxane; water T=55°C; ΔH(excit.), ΔS(excit.), ΔG(excit.), kinetic solvent isotope kH/kD effect in the hydrolysis, substituent and temperature effect; Thermodynamic dataRate constantKinetics;
参考文献
Journal of Organic Chemistry, , vol. 59, # 6 p. 1369 - 1374
sulfuric acid in 1,4-dioxane; water T=55°C; ΔH(excit.), ΔS(excit.), ΔG(excit.), kinetic solvent isotope kH/kD effect in the hydrolysis, substituent and temperature effect; Thermodynamic dataRate constantKinetics;
参考文献
Journal of Organic Chemistry, , vol. 59, # 6 p. 1369 - 1374
sodium tetrahydroborate; hydrogen; Pd-6 in isopropyl alcohol T=50°C; P=760 Torr; 0.5 h; other catalysts (immobilized complexes of palladium); Product distribution;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 34, # 8 p. 1568 - 1572
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 8 p. 1716 - 1721
water in acetonitrile T=25°C; other glutathione - subst. nitrosobenzene semimercaptals; ΔH(excit.), ΔS(excit.); var. temp.; pH 7.49; also in the presence of var. acids; mechanism; KineticsThermodynamic dataRate constant;
参考文献
Journal of the American Chemical Society, , vol. 114, # 8 p. 3052 - 3059