in tetrachloromethane; pentane byproducts: (t-Bu)3SiH, (t-Bu)3SiCl; Cl2 in CCl4 was reacted with Ga-compd. in pentane at -78 °C; unidentified products were also formed;
参考文献
Wiberg, Nils; Blank, Thomas; Amelunxen, Kerstin; Noeth, Heinrich; Schnoeckel, Hansgeorg; et al.
European Journal of Inorganic Chemistry, 2002 , p. 341 - 350
in n-heptane byproducts: NaCl; soln. of Na-supersilyl*2THF in heptane added dropwise to a soln. of (supersilyl)2-GaCl in heptane at -78°C, warmed to room temp.; all volatiles removed, NaCl removed by filtration, soln. volume reduced,after 0.5 days at -23°C (supersilyl)2 removed, after 5 days at - 23°C product formed;
参考文献
Wiberg, Nils; Blank, Thomas; Amelunxen, Kerstin; Noeth, Heinrich; Knizek, Joerg; Habereder, Tassilo; Kaim, Wolfgang; Wanner, Matthias
European Journal of Inorganic Chemistry, 2001 , # 7 p. 1719 - 1727
in n-heptane byproducts: NaCl; reagents mixed in heptane at -78°C, after 6 h, react. mixt. warmed to room temp.; volatiles removed, filtered, volume reduced, within 1 day at -23°C crystals obtained;
参考文献
Wiberg, Nils; Blank, Thomas; Amelunxen, Kerstin; Noeth, Heinrich; Knizek, Joerg; Habereder, Tassilo; Kaim, Wolfgang; Wanner, Matthias
European Journal of Inorganic Chemistry, 2001 , # 7 p. 1719 - 1727
in pentane byproducts: NaN(SiMe3)2; under dry Ar or N2, 1 equiv. of Na-compd., 72 h at -90 °C, warming to -30 °C; soln. was concd., crystn. at -23 °C for 14 d;
参考文献
Wiberg, Nils; Blank, Thomas; Amelunxen, Kerstin; Noeth, Heinrich; Schnoeckel, Hansgeorg; et al.
European Journal of Inorganic Chemistry, 2002 , p. 341 - 350
