反应条件
Al; AlCl3 in tetrahydrofuran; ethylene glycol dimethyl ether (under Ar, Schlenk); flask charged with Al, AlCl3, ligand added, stirredat room temp. for 1 h, CrCl3 added, heated at 120°C for 5 h, coo led, mixt. of THF-DME added, refluxed for 8 h, cooled to room temp.; ppt. filtered, washed with heptane, solvent removed in vacuo, ppt. extd.with heptane, filtered, heptane stripped off, solid sublimed at 105.deg ree.C/0.01 mmHg;
参考文献
Calucci, Lucia; Cloke, F. Geoffrey N.; Englert, Ulli; Hitchcock, Peter B.; Pampaloni, Guido; Pinzino, Calogero; Puccini, Filippo; Volpe, Manuel
Dalton Transactions, 2006 , # 35 p. 4228 - 4234
