in gaseous matrix byproducts: HCl, H2; Ar carrier gas, room temp., static vac. glass reactor with quartz window (reaction mixt. made up in reactor); manometric monitoring, chemiluminescence spectroscopy;
参考文献
Kinetics and Catalysis, , vol. 27, # 6 pt 1 p. 1120 - 1126
in neat (no solvent) byproducts: calcium silicide; reaction by leading SiCl4-vapour over an excess of heated CaH2-powder under red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and Ca-silicide as solid products;;
参考文献
Ca: MVol.B2, 6, page 275 - 277
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 148, p. 555 - 557
in neat (no solvent) reaction by leading an excess of SiCl4-vapour over heated CaH2-powder above red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and amorpheous Si as solid products;;
参考文献
Ca: MVol.B2, 6, page 275 - 277
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 148, p. 555 - 557
