in neat (no solvent) HSiCl3 and dodecene at 300°C under pressure;;
参考文献
Sommer; Pietrusza; Whitmore
Journal of the American Chemical Society, 1947 , vol. 69, p. 188
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Gmelin Handbook: Si: MVol.C, 53, page 153 - 155
catalyst: anion exchange resin in gas Kinetics; byproducts: SiCl4; mixt. of Ar and SiHCl3 is passed over the catalyst (anion exchange resins AV17-12P with active group -N(+)Me3, AV27-10P with active group -N(+)Me2C2H5O, AN18-12P with active group -N(+)HMe2) at 388 K; react. is monitored by chromy.;
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 32, p. 561 - 562
Zhurnal Neorganicheskoi Khimii, , vol. 32, p. 1002 - 1005
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 12 h; not isolated; IR spectroscopy (identified 41percent SiCl2H2 and 15percent SiH4 in product mixt.);
