in neat (no solvent) react. on heating at 250 °C for a longer period of time;;
参考文献
Gmelin Handbook: P: MVol.C, 204, page 467 - 469
→
反应条件
in neat (no solvent) heating with an excess of Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2;;
in neat (no solvent) heating a mixt. of POCl3 and P2O5 (molar ratio 2:1 - 5:1) for 48 h; formation of a product containing POCl3, P2O3Cl4, P3O6Cl3 and a small amount of condensated phosphoryl chlorides P(n)O(2n-1)Cl(2n+2);;
参考文献
Grunze, H.
Z. Anorg. Chem., 1958 , vol. 296, p. 63 - 72
Full Text Show Details
Gmelin Handbook: P: MVol.C, 205, page 469 - 471
in neat (no solvent) heating a mixt. of POCl3 and P2O5 (molar ratio POCl3:P2O5 > 4) for 48 h; formation of a product containing POCl3, P2O3Cl4, P3O6Cl3; no formation of polyphosphoryl chlorides;;
参考文献
Grunze, H.
Z. Anorg. Chem., 1958 , vol. 296, p. 63 - 72
Full Text Show Details
Gmelin Handbook: P: MVol.C, 205, page 469 - 471
→
反应条件
in neat (no solvent) byproducts: Hg-phosphate; heating with an excess of POCl3 with Hg in a sealing tube at 250 °C for 15 h; formation of PCl3 and a small amount of P2O5, P2O3Cl4 and Hg2Cl2, HgCl2 and Hg-phosphate;;
in trichlorophosphate byproducts: POI3; on heating a soln. of HI in POCl3 for 48h;; precipitation of PI3-crystals;;
参考文献
Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1896 , vol. 122, p. 814 - 817
Full Text Show Details
Gmelin Handbook: P: MVol.C, 227, page 520 - 522
