15 Stdn. auf 120grad (Badtemperatur),24 Stdn. auf 150grad,15 Stdn. auf 170grad u. weitere 15 Stdn. auf 200grad u. behandelt das Reaktionspr. mit Wasser;
参考文献
Michaelis
Justus Liebigs Annalen der Chemie, 1915 , vol. 407, p. 295
in neat (no solvent)
passing POCl3 vapor over CaF2 heated at 150 °C;; products contains 35 percent PF3, 25 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 212, page 487 - 489
in neat (no solvent)
addn. of 80 g SbF3 to a mixt. of 200 g POCl3 and 50 g SbCl5 at 75 °C and 190-200 Torr;; products contains 55 percent PF3, 5 percent POF2Cl and 40 percent POFCl2;;
参考文献
Booth, H. S.; Dutton, F. B.
Journal of the American Chemical Society, 1939 , vol. 61, p. 2937 - 2940
Full Text View citing articles Show Details
Gmelin Handbook: P: MVol.C, 212, page 487 - 489
in acetonitrile
fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
in acetonitrile
fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
