反应条件
water in neat (no solvent)
slow addn. of 1 mol H2O to 1 mol POCl3 (14 days); formation of hydrated POCl3; evolution of HCl completed after 3 weeks, then heating at 60 °C at 12 Torr; storing the viscous product in sealed vials for 4 years;; formation of trimeta-, mono-, di- and small amounts of polyphosphoric acid chloride; further hydrolysis and condensation forming Cl2OPOH, Cl2OPOP(O)ClOH, Cl2OPOPO2ClPOClOH and P3O6Cl3;;
参考文献
Roux, H.; Thilo, E.; Grunze, H.; Viscontini, M.
Helvetica Chimica Acta, 1955 , vol. 38, p. 15 - 21
Full Text Show Details
Viscontini, M.; Bonetti, G.
Helvetica Chimica Acta, 1951 , vol. 34, p. 2435 - 2437