in neat (no solvent) Kinetics; mixt. of Pt and KCl charged into a quartz cell which is placed in a resistance furnace, when KCl melted, Cl2 is bubbled through the melt at a temp. of 800-1000°C; x-ray diffraction;
参考文献
Journal of applied chemistry of the USSR, , vol. 60, # 1 pt 1 p. 8 - 11
silver nitrate in water byproducts: AgI; stirring a mixt. of K2PtCl4 and KI in water at room temp. for 3 h and addn. of cylopropylamine, filtering the cis-(C3H5NH2)PtI2 intermediate after 1 h, treating the intermediate with aq. AgNO3, filtering off formed AgI and addn. of KCl to the filtrate; keeping the mixt. at 6°C for 2 d, filtering off the formed cis-(C3H5NH2)2PtCl2 complex, washing with water, methanol and diethyl ether and drying under vacuum, elem. anal.;
sodium hydroxide in water an aq. soln. of K2PtCl4 was added to a soln. of the ligand in water at pH 6, the mixt. was stirred under successive adjustment of pH to 5-6 with0.1 N NaOH until pH was no longer changed; ppt. was filtered off, washed with water and EtOH and dried;
in hydrogenchloride reaction mixture was held at 55°C for 72 h, then at 7°C for 10 h in absence of light and oxygen;; filtered, washed with water, dried under vacuum;;
参考文献
Howell; Beholz; Sastry
Journal of thermal analysis, 1993 , vol. 40, # 2 p. 395 - 403
potassium hydroxide in ethanol under argon, at 35-40°C, for 48 h; evapd. in vac., residue extd. with hexane, ext. concd. and cooled, crystn.; elem. anal.;
参考文献
Goel, Ram G.; Ogini, William O.; Srivastava, Ramesh C.
Journal of Organometallic Chemistry, 1981 , vol. 214, # 3 p. 405 - 417
in water dissoln. of 2.64 mmol of 4-cyanopyridine in a minimum amount of water; addn. to a stirred soln. of 1.205 mmol K2(PtCl4) in distilled water; stirring for several hours; storing in a refrigerator; pptn.; filtration;; washing twice with ice-water, ice-ethanol and ether; drying in vac. over P2O5; elem. anal.;;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 2 p. 233 - 236
in ethanol; dichloromethane; water mixing aq. K2PtCl4 with ligand (in CH2Cl2), EtOH addn., heating (4 h); concn.; elem. anal.;
参考文献
Hartley, Frank R.; Murray, Stephen G.; Levason, William; Soutter, Helen E.; McAuliffe, Charles A.
Inorganica Chimica Acta, 1979 , vol. 35, p. 265 - 278
in not given formation on treatment of 1 mol K2(PtCl4) with 4 mol Se(CH3)2;;
参考文献
Fritzmann, E. Ch.
Z. Anorg. Chem., 1912 , vol. 73, p. 239 - 255
Full Text Show Details
Fritzmann, E. Ch.
Izv. Plat., 1926 , vol. 4, p. 182 - 202
Full Text Show Details
Gmelin Handbook: Pt: MVol.D, 152, page 337 - 338
in water shaking of 1 mol K2(PtCl4) in aq. soln. with 2 mol Se(CH3)2 at 20°C;; washing with H2O and drying between paper; dissolving in CHCl3;;
参考文献
Fritzmann, E. Ch.
Z. Anorg. Chem., 1912 , vol. 73, p. 239 - 255
Full Text Show Details
Fritzmann, E. Ch.
Izv. Plat., 1926 , vol. 4, p. 182 - 202
Full Text Show Details
Gmelin Handbook: Pt: MVol.D, 152, page 337 - 338
in water inert atmosphere; stirring K2PtCl4 with excess Et2S at room temp. for 24h, removal of excess Et2S, KPF6 addn., stirring for few h; evapn., washing (water), collection (filtration), washing (water), drying in air;
参考文献
Wendt, Ola F.; Oskarsson, Ake; Leipoldt, Johann G.; Elding, Lars I.
Inorganic Chemistry, 1997 , vol. 36, # 20 p. 4514 - 4519
