pyridine hydrochloride in chloroform to the soln. of SiI4/CHCl3 the soln. of pyridinium chloride/CHCl3 was added dropwise with stirring, stirred at 298°C under protective gas; gas chromy.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 483, p. 140 - 144
hydrogenchloride; lithium aluminium tetrahydride in benzene Kinetics; introduction of HCl gas into a soln. of Si5Cl12 and a very few trimethylamine, at room temp.; detection by Raman and (1)H-NMR;
in neat (no solvent) byproducts: Cu; CuCl particles were deposited on a Si wafer by dipping in a slurry of CuCl in hexane; coated wafer was heated at 380°C in a furnace for 1-60 min;; mixt. not sepd.;;
in neat (no solvent) Kinetics; mixt. of Cu3Si (from self-propagation react.) and CuCl (molar ratio 1.50:1.00) manually ground at room temp. under inert atmosphere for 15 min;evacuated; outgassed in vac. for 1 h at room temp. and for 1 h at 70°C; heated to 145-210°C; detd. by X-ray diffraction; monitored by thermogravimetry;
