in gas High Pressure; reagents added to tube in dry ice bath, sealed in amts. to develop about 30-50 atm of pressure at 300°C, heated at 310-350°C for 1.5-69 h; analyzed by GLC;
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3, (t-C4H9)(i-C3H7)PSi2Cl5; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 2.5 h; (119)Sn- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 75 d; (119)Sn- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
in gas byproducts: bis(trichlorosilyl)metane, bis(trichlorosilyl)ethane, bis(trichlorosilyl)ethylene; passing through tubular reactor (500°C, contact time 30 s); yields depending on temperature; product sepn. by distillation;
参考文献
Russian Journal of General Chemistry, , vol. 66, # 7 p. 1113 - 1116
in neat (no solvent) Kinetics; CuCl and Si2Fe mixt. heated in evac. glass tube reactor (0.1 Pa) at 250-310°C, SiCl4 condn. in liquid nitrogen trap; monitoring by TG;
参考文献
Journal of Materials Science, , vol. 27, p. 1337 - 1342
