co-catalyst: P(OMe)3; tri-n-butyl-tin hydride in toluene absence of air; H2-stream; further alternate co-catalysts: PCy3 or PBu3 or N-methylimidazole or pyridine or chinoline; gas chromy.;
参考文献
Paetzold; Roewer; Herzog
Journal of Organometallic Chemistry, 1996 , vol. 508, # 1-2 p. 147 - 152
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 36 h; not isolated; IR spectroscopy (identified 25-30percent SiCl3H, 15percent SiCl2H2 and 10percent SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
