in neat (no solvent) byproducts: calcium silicide; reaction by leading SiCl4-vapour over an excess of heated CaH2-powder under red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and Ca-silicide as solid products;;
参考文献
Gmelin Handbook: Ca: MVol.B2, 6, page 275 - 277
Full Text Show Details
Besson, A.; Fournier, L.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 555 - 557
in gas reactor temp.: 250 - 500°C; detn. by gas chromy.;
参考文献
Mulla, I. S.; Choube, A. C.; Dongare, M. K.; Sinha, A. P. B.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1988 , vol. 27, # 9 p. 756 - 758
in neat (no solvent) reaction by leading an excess of SiCl4-vapour over heated CaH2-powder above red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and amorpheous Si as solid products;;
参考文献
Gmelin Handbook: Ca: MVol.B2, 6, page 275 - 277
Full Text Show Details
Besson, A.; Fournier, L.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 555 - 557
Mg in diethyl ether addn. of a mixt. of SiCl4 and CH2CHCH2I to Mg in ether;; distn.;;
参考文献
Petrov, A. D.; Shchukovskaja, L. L.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1952 , p. 564 - 565
C. A., 1953 , p. 3792
Full Text Show Details
Gmelin Handbook: Si: MVol.C, 15, page 44 - 48
