in further solvent(s)
react. in tetrachlorethane at 100 °C;;
参考文献
Becke-Goehring, M.; Gehrmann, W.; Goetze, W.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1963 , vol. 326, p. 127 - 138
Full Text Show Details
Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in not given
react. with OP(NH2)3; removal of formed HCl with dry air;;
参考文献
Becke-Goehring, M.; Mann, T.; Euler, H. D.
Chemische Berichte, 1961 , vol. 94, p. 193 - 198
Full Text Show Details
Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in not given
react. of an excess of PCl5 with OP(NH2)3 without removal of formed HCl; primary formation of OP(NH2)2Cl, condensation forming ((NH)2(POCl2)2)(n); further react. with PCl5 forming POCl3, NH3 and (PNCl2)(n);;
参考文献
Becke-Goehring, M.; Mann, T.; Euler, H. D.
Chemische Berichte, 1961 , vol. 94, p. 193 - 198
Full Text Show Details
Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in trichlorophosphate
byproducts: Cl2(O)P(NPCl2)5Cl; under reflux; treatment of the crude product with n-heptane, products identified in the sol. and in the insol. phase with NMR spectroscopy;
参考文献
Abouchaccra, Taher; Helioui, Moncef; Puskaric, Emile; Jaeger, Roger de; Heubel, Joseph
Journal of Chemical Research, Synopses, 1981 , p. 230 - 231
