in neat (no solvent)
byproducts: PF5; react. of solid PCl5 with SbF3;;
参考文献
Booth, H. S.; Swinehart, C. F.
Journal of the American Chemical Society, 1932 , vol. 54, p. 4751 - 4753
View citing articles Show Details
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
in further solvent(s)
dissolving PCl5 in AsCl3; addn. of AsF3 drop by drop; pptn. on cooling, evolution of PF3 after completation of react.;; isolation of ppt., washing with AsCl3, removal of AsCl3 by a stream of air;;
in acetonitrile
byproducts: PF5*CH3CN; fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
in acetonitrile
byproducts: PF5*CH3CN; fluoride to P molar ratio from 1:1 to 2:1, a soln. of P compd. frozen inliq. N2, ftoride added, gradually heated, or reacted at room temp.; soln. separated, not isolated, detected by NMR;
参考文献
Kokunov; Ershova; Razgonyaeva
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002 , vol. 28, # 7 p. 461 - 463
