in dichloromethane
inert atmosphere; dropwise addn. of 0.5-1 equiv. PCl5 to amine at -78 or25°C, stirring for 30 min to 12 h; yields depending on educt rat io, reaction temp., time and rate of addn.; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Allcock, Harry R.; Crane, Chester A.; Morrissey, Christopher T.; Olshavsky, Michael A.
Inorganic Chemistry, 1999 , vol. 38, # 2 p. 280 - 283
Ruegheimer
Chemische Berichte, 1884 , vol. 17, p. 737
Chemische Berichte, 1885 , vol. 18, p. 2978
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Ruegheimer
Chemische Berichte, 1885 , vol. 18, p. 2977,2978