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乙二醇
甲醛
63148-62-9
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二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1002754-12-2
合成路线
（共 9 条）
1002754-12-2
→
反应条件
72741-87-8
八倾吲嗪三醇
反应条件
1: para-toluenesulfonic acid monohydrate / acetone / 0 °C 2: TBAF / tetrahydrofuran / 20 °C 3: triethylamine / CH2Cl2 / 0 °C 4: H2 / Pd(OH)2/C / ethanol; tetrahydrofuran / 20 °C / 5171.48 Torr 5: aq. HCl / tetrahydrofuran / 20 °C View Scheme
参考文献
Guo, Haibing; O'Doherty, George A.
Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-01-9
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反应条件
1002754-12-2
反应条件
With osmium(VIII) oxide; 4-methylmorpholine N-oxide in acetone; tert-butyl alcohol Upjohn dihyroxylation; 24 h;
参考文献
Guo, Haibing; O'Doherty, George A. Tetrahedron, 2008 , vol. 64, # 2 p. 304 - 313
1002754-03-1
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反应条件
1002754-12-2
反应条件
Multi-step reaction with 6 steps 1: DMAP / CH2Cl2 / -78 °C2: Pd2(DBA)3*CHCl3; triphenylphosphine / CH2Cl2 / 0 - 20 °C3: NaBH4 / CH2Cl2; methanol / -78 °C4: pyridine; DMAP / CH2Cl2 / 20 °C5: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C6: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-27-9
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反应条件
1002754-12-2
反应条件
Multi-step reaction with 5 steps 1: Pd2(DBA)3*CHCl3; triphenylphosphine / CH2Cl2 / 0 - 20 °C2: NaBH4 / CH2Cl2; methanol / -78 °C3: pyridine; DMAP / CH2Cl2 / 20 °C4: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C5: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-04-2
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反应条件
1002754-12-2
反应条件
Multi-step reaction with 4 steps 1: NaBH4 / CH2Cl2; methanol / -78 °C2: pyridine; DMAP / CH2Cl2 / 20 °C3: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C4: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-11-1
→
反应条件
1002754-12-2
反应条件
Multi-step reaction with 2 steps 1: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C2: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
120853-04-5
→
反应条件
1002754-12-2
反应条件
Multi-step reaction with 9 steps 1: 98 percent / imidazole / dimethylformamide / 0 - 20 °C2: formic acid; triethylamine / Ru(η6-mesitylene)-(R,R)-TsDPEN / CH2Cl2 / 20 °C3: NBS; H2O; NaHCO3 / NaOAc*3H2O / tetrahydrofuran / 0 °C4: DMAP / CH2Cl2 / -78 °C5: Pd2(DBA)3*CHCl3; triphenylphosphine / CH2Cl2 / 0 - 20 °C6: NaBH4 / CH2Cl2; methanol / -78 °C7: pyridine; DMAP / CH2Cl2 / 20 °C8: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C9: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-12-2
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 2 steps 1: para-toluenesulfonic acid monohydrate / acetone / 0 °C2: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-12-2
→
反应条件
1002754-14-4
反应条件
Multi-step reaction with 3 steps 1: para-toluenesulfonic acid monohydrate / acetone / 0 °C2: TBAF / tetrahydrofuran / 20 °C3: triethylamine / CH2Cl2 / 0 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
