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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1002754-13-3
合成路线
（共 9 条）
1002754-13-3
→
反应条件
72741-87-8
八倾吲嗪三醇
反应条件
1: triethylamine / CH2Cl2 / 0 °C 2: H2 / Pd(OH)2/C / ethanol; tetrahydrofuran / 20 °C / 5171.48 Torr 3: aq. HCl / tetrahydrofuran / 20 °C View Scheme
参考文献
Guo, Haibing; O'Doherty, George A.
Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-10-0
→
反应条件
1002754-13-3
反应条件
With tetrabutyl ammonium fluoride in tetrahydrofuran T=20°C; 12 h;
参考文献
Guo, Haibing; O'Doherty, George A. Tetrahedron, 2008 , vol. 64, # 2 p. 304 - 313
1002754-03-1
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 8 steps 1: DMAP / CH2Cl2 / -78 °C2: Pd2(DBA)3*CHCl3; triphenylphosphine / CH2Cl2 / 0 - 20 °C3: NaBH4 / CH2Cl2; methanol / -78 °C4: pyridine; DMAP / CH2Cl2 / 20 °C5: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C6: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone7: para-toluenesulfonic acid monohydrate / acetone / 0 °C8: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-27-9
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 7 steps 1: Pd2(DBA)3*CHCl3; triphenylphosphine / CH2Cl2 / 0 - 20 °C2: NaBH4 / CH2Cl2; methanol / -78 °C3: pyridine; DMAP / CH2Cl2 / 20 °C4: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C5: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone6: para-toluenesulfonic acid monohydrate / acetone / 0 °C7: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-04-2
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 6 steps 1: NaBH4 / CH2Cl2; methanol / -78 °C2: pyridine; DMAP / CH2Cl2 / 20 °C3: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C4: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone5: para-toluenesulfonic acid monohydrate / acetone / 0 °C6: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-01-9
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 3 steps 1: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone2: para-toluenesulfonic acid monohydrate / acetone / 0 °C3: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-11-1
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 4 steps 1: TMSN3 / allylpalladium chloride dimer; 1,4-bis(diphenylphosphino)butane / tetrahydrofuran / 50 °C2: N-methylmorpholine N-oxide; water / OsO4 / 2-methyl-propan-2-ol; acetone3: para-toluenesulfonic acid monohydrate / acetone / 0 °C4: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-12-2
→
反应条件
1002754-13-3
反应条件
Multi-step reaction with 2 steps 1: para-toluenesulfonic acid monohydrate / acetone / 0 °C2: TBAF / tetrahydrofuran / 20 °C
参考文献
Guo, Haibing; O'Doherty, George A. Organic Letters, 2006 , vol. 8, # 8 p. 1609 - 1612
1002754-13-3
+
124-63-0
甲烷磺酰氯
→
反应条件
1002754-14-4
反应条件
With triethylamine in dichloromethane T=0°C; 0.5 h;
参考文献
Guo, Haibing; O'Doherty, George A. Tetrahedron, 2008 , vol. 64, # 2 p. 304 - 313
