in neat (no solvent)
Kinetics; synthesis of O3 from air in a barrier discharge using ceramic electrodes with varying dielectric constants; not isolated, detected spectrophotometrically;
参考文献
Gibalov, V. I.; Volodin, V. E.; Samoilovich, V. G.
Russian Journal of Physical Chemistry, 1989 , vol. 63, # 10 p. 1541 - 1543
Zhurnal Fizicheskoi Khimii, 1989 , vol. 63, p. 2804 - 2807
in solid matrix
byproducts: O3*O; Irradiation (UV/VIS); photolysis at 266 nm for 120 min in solid O2; not isolated, detected by IR;
参考文献
Coanga; Schriver-Mazzuoli; Schriver; Dahoo
Chemical Physics, 2002 , vol. 276, # 3 p. 309 - 320
→
反应条件
in gaseous matrix
Irradiation (UV/VIS); rotating metal target irradiation with Nd:YAG laser (1064 nm, 10 Hz, 10 ns, 40-50 mJ/pulse), metal atoms codeposition with 0.5percent (16)O2/0.5percent (18)O2/0.5percent (16)O(18)O/Ar at 2-4 mmol/h for 1-3 h at 10 K, eventual annealing up to 35 K;
参考文献
Chertihin, George V.; Bare, William D.; Andrews, Lester
Journal of Chemical Physics, 1997 , vol. 107, # 8 p. 2798 - 2806
in solid matrix
byproducts: Ag(η1-OO); laser-ablated Ag atoms co-deposited (2-4 mmol/h) with 0.25percent CO + 0.5percent O2in Ar on CsI window (7 K, 1 h); annealed (25 or 30 K); not isolated;
参考文献
Xu, Qiang; Jiang, Ling
Journal of Physical Chemistry A, 2006 , vol. 110, # 8 p. 2655 - 2662
in gas
Kinetics; byproducts: NO3; description of processes in a barrier discharge during electrosynthesisof O3; investigation of effect of power of discharge, working frequencyof power supply, flow rate, temp. and pressure of gas; determination ofrate constants for main reactions;; monitoring of concns. of oxides and O3 by mass spectroscopy;;
参考文献
Samoilovich, V. G.; Gibalov, V. I.
Russian Journal of Physical Chemistry (Translation of Zhurnal Fizicheskoi Khimii), 1986 , vol. 60, p. 1107 - 1116
Zhurnal Fizicheskoi Khimii, 1986 , vol. 60, p. 1841 - 1853
