chlorine in neat (no solvent)
chain reaction; mechanism discussed;;
参考文献
Norrish, R. G. W.; Neville, G. H. J.
Journal of the Chemical Society, 1934 , p. 1864 - 1872
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Gmelin Handbook: O: MVol.4, 22, page 1034 - 1037
in neat (no solvent)
other Radiation; reaction by irradiation with blue light;; condensation of ClO3 on the walls of the vessel at 0°C;;
参考文献
Rollefson, G. K.; Byrns, A. C.
Journal of the American Chemical Society, 1934 , vol. 56, p. 364 - 367
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Gmelin Handbook: O: MVol.4, 75, page 1149 - 1151
in neat (no solvent)
other Radiation; reaction by exposure of the mixture at 30°C;;
参考文献
Byrns, A. C.; Rollefson, G. K.
Journal of the American Chemical Society, 1934 , vol. 56, p. 1250 - 1251
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Gmelin Handbook: O: MVol.4, 75, page 1149 - 1151
in neat (no solvent)
byproducts: Cl2O2; prepn. by interaction of ozone (initial pressure was 1.0 torr) with chlorinated methanes adsorbed on a thin ice film over the temperature range 210-292 K; not isolated; monitored by IR spectroscopy;
参考文献
Vysokikh; Mukhamedzyanova; Yagodovskaya; Savilov; Lunin
Russian Journal of Physical Chemistry A, 2007 , vol. 81, # 11 p. 1836 - 1839
in neat (no solvent)
byproducts: ClO2, Cl2O7; prepn. by interaction of ozone (initial pressure was 1.0 torr) with chlorinated methanes adsorbed on a thin ice film over the temperature range 210-292 K; not isolated; monitored by IR spectroscopy;
参考文献
Vysokikh; Mukhamedzyanova; Yagodovskaya; Savilov; Lunin
Russian Journal of Physical Chemistry A, 2007 , vol. 81, # 11 p. 1836 - 1839
