oxygen in solid matrix
arsenic sublimed at 300-375°C into an argon/O2 stream, passed through a low-power open microwave discharge for 4 h, codeposited at 15+/-2 K; detn. by IR-spectroscopy;
O2 in neat (no solvent, gas phase)
Kinetics; Electric Arc; electric discharge, natural O2 with 3percent (18)O2, 100 Torr; high enhancement ozone generated in vessel at room temp., cryogenically seperated; low enhancement ozone produced and collected at 77 K in pyrex vessel; further products; ratio of products detected by mass spectroscopy;
参考文献
Anderson, S. M.; Morton, J.; Mauersberger, K.
Chemical Physics Letters, 1989 , vol. 156, p. 175 - 180
electron in gaseous matrix
Irradiation (UV/VIS); 1064 nm Nd:YAG laser focusing on Ni or Cu target, metal atoms and electrons with 0.2percent O2/Ne codeposition for 2-6 h onto 4 K substrate, accordingto T. R. Burkholder, L. Andrews, J. Chem. Phys. 95 (1991) 8697;
参考文献
Zhou, Mingfei; Hacaloglu, Jale; Andrews, Lester
Journal of Chemical Physics, 1999 , vol. 110, # 19 p. 9450 - 9456
nickel sulfide in neat (no solvent)
Kinetics; catalytic oxidn. of CS2, O2-N2-C2H4-mixture is passed over Ni2S3 and mixed with CS2-vapor, O2 in excess, mechanism discussed;; yield of SO2 between 140 and 330°C independent from CS2-concn.;;
参考文献
Griffith, R. H.; Hill, S. G.
Journal of the Chemical Society, 1938 , p. 2037 - 2040
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Gmelin Handbook: S: MVol.B1, 88, page 194 - 196
air in neat (no solvent)
spontaneous luminescence below ignition temp.;;
参考文献
Bloch, L.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 148, p. 782 - 783
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Gmelin Handbook: S: MVol.B1, 74, page 164 - 166
in not given
Electrolysis; reaction by use of a H2SO4 soln. at cooling with fluid water for a period of 24 hours;; O3/O2 concentration in 910 cm*cm*cm: 1250 mg/6.6 mg;;
参考文献
Berthelot, M.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1878 , vol. 86, p. 71 - 76
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Berthelot
Ann. Chim. Phys., 1878 , vol. 14, p. 354 - 361
