in neat (no solvent)
Kinetics; discharge flow reactor; T = 298 K; Br atoms were produced by microwave discharge of Br2 diluted with He; laser induced fluorescence; mass spectrometry;
参考文献
Poulat, G.; Laverdet, G.; Bras, G. Le
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Gaines,D.F.; Schaeffer,R.
Journal of the American Chemical Society, 1963 , vol. 85, p. 3592 - 3594
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Gmelin Handbook: B: B-Verb.4, 4.3, page 108 - 110
Mayes, H. A.; Partington, J. R.
Journal of the Chemical Society, 1926 , p. 2594 - 2605
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Gmelin Handbook: S: MVol.B3, 159, page 1866 - 1868
H2O in water
vigorous reaction with H2O, intermediate (PBr3OH)Br decomposes into HBr and POBr3, which precipitates first as white flakes and then is hydrolyzed to PO4(3-);;
参考文献
Kolditz, L.; Bauer, K.
Z. Anorg. Chem., 1959 , vol. 302, p. 241 - 252
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Gmelin Handbook: P: MVol.C, 222, page 509 - 511
Jonas, H.
Z. Anorg. Chem., 1951 , vol. 265, p. 273 - 283
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Gmelin Handbook: S: MVol.B3, 160, page 1868 - 1870
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Jonas, H.
in: FIAT Review, Bd. 23, S. 193
Drake; Sweeney
Journal of Organic Chemistry, 1946 , vol. 11, p. 67,71
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Graham et al.
Journal of the Chemical Society [Section] C: Organic, 1969 , p. 68
