in gaseous matrix
Kinetics; Irradiation (UV/VIS); Br radical (generated from CF2Br2) by laser flash photolysis at 266nm or from Br2 at 355nm in N2/H2 gas mixt. with H2S at temp. between 273 and 431K; not isolated, detected by time resolved fluorescence spectrometry;
参考文献
Nicovich, J. M.; Kreutter, K. D.; Dijk, C. A. van; Wine, P. H.
Journal of Physical Chemistry, 1992 , vol. 96, # 6 p. 2518 - 2528
→
反应条件
in neat (no solvent)
参考文献
Long, L. H.; Dollimore, D.
Journal of the Chemical Society, 1951 , p. 1608 - 1612
in neat (no solvent)
heating equiv. amts. of starting material on a water bath (evolution of HBr); on further addition of POBr3 at 100 to 150°C two layers form, the bottom layer contains H4P2O7 but no HPO3, whether P2O3Br4 forms is possible, but not proved;;
参考文献
Balarew, D.
Z. Anorg. Chem., 1921 , vol. 118, p. 123 - 130
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Gmelin Handbook: P: MVol.C, 221, page 508 - 509
→
反应条件
sulfur dioxide; water
oxidized As2O3/SO2 ratio depends on H(1+)-conc.;
参考文献
Luther, R.; Schilow, N.
Z. phys. Ch., 1903 , vol. 46, p. 777 - 812
Full Text Show Details
Gmelin Handbook: S: MVol.B2, 1.6.2.4, page 519 - 520
in neat (no solvent)
Kinetics; Irradiation (UV/VIS); flash photolysis of mixtures of H2S and IBr at 296 K in presence of quenchers;; not isolated; detection by atomic resonance spectroscopy;;
参考文献
Boriev, I. A.; Gordon, E. B.; Efimenko, A. A.
Chemical Physics Letters, 1985 , vol. 120, p. 486 - 490
in neat (no solvent)
reaction in a sealed tube at 270°C;;
参考文献
Royen, P.; Hill, K.
Z. Anorg. Chem., 1936 , vol. 229, p. 112 - 128
→
反应条件
in neat (no solvent)
Kinetics; vapor phase hydrolysis of (241)AmBr3 (prepared from (241)Am(III) hydroxide and HBr-gas at 500-590°C) at 718-890 K in a hydrolysis apparatus described in : Weigel, F.; Wishnevsky, V. Gueldner, R., J. Less-Common Met. 75 (1980) 89.;
参考文献
Weigel, F.; Wishnevsky, V.; Gueldner, R.
Journal of the Less-Common Metals, 1982 , vol. 84, p. 147 - 156
in neat (no solvent)
using N2 as a carrier gas; heating at 473 - 493 K using the hot tube method according to: C.A. Brown and A. W. Laubengayer, J. Am. Chem. Soc. 77, 3699 (1955);
参考文献
Kazakov; Timoshkin
Russian Journal of Inorganic Chemistry, 2012 , vol. 57, # 4 p. 557 - 563
