in pentane byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe;
参考文献
Journal of Organometallic Chemistry, , vol. 232, # 2 p. 137 - 146
in hexane Ar-atmosphere; dropwise addn. of GeCl4 to 2 equiv. of Li-compd. (-78°C, stirring (-78°C, 12 h), slow warming to ambient temp., stirring (36 h); product mixt. not sepd., detd. by (1)H-NMR spectroscopy;
参考文献
Mallela, S. P.; Geanangel, R. A.
Inorganic Chemistry, 1994 , vol. 33, p. 1115 - 1120
