in further solvent(s)
byproducts: H2DO(1+), HD2O(1+), Ge(OH)(x)Cl(4-x)(OH); mixt. of D2O and H2O dissolved in GeCl4 at > 1E-2 mol/l concn.; detd. by IR spectra;
in diethyl ether; hexane
byproducts: LiCl; (N2); Schlenk technique or glovebox; soln. of Li compd. (2 equiv.) in Et2O was added dropwise to soln. of GeCl4 (1 equiv.) in hexane at -78°C; soln. was warmed to room temp. and stirred for 4 h; filtered; solvents removed (vac.); oily residue filtered; distd. (0.01 Torr, 85°C); filtered-off residue washed (hexane); elem. anal.;
参考文献
Batsanov, Andrei S.; Cornet, Stephanie M.; Dillon, Keith B.; Goeta, Andres E.; Thompson, Amber L.; Xue, Bao Yu
Dalton Transactions, 2003 , # 12 p. 2496 - 2502
in diethyl ether; hexane
byproducts: LiCl; (N2); Schlenk technique or glovebox; soln. of Li compd. (2 equiv.) in Et2O was added dropwise to soln. of GeCl4 (1 equiv.) in hexane at -78°C; soln. was warmed to room temp. and stirred for 4 h; filtered; solvents removed (vac.); oily residue filtered; distd. (0.01 Torr, 85°C); filtered-off residue washed (hexane); elem. anal.;
参考文献
Batsanov, Andrei S.; Cornet, Stephanie M.; Dillon, Keith B.; Goeta, Andres E.; Thompson, Amber L.; Xue, Bao Yu
Dalton Transactions, 2003 , # 12 p. 2496 - 2502
