ethoxylated alkylphenols mixt. in cyclohexane; water
mixing AgNO3 and NaH2PO2 microemulsions at room temp.; detd. by x-ray scattering and electron spectroscopy;
ethoxylated alkylphenols mixt. in cyclohexane; water
mixing AgNO3 and NaH2PO2 microemulsions at room temp.; detd. by x-ray scattering and electron spectroscopy;
byproducts: NaCl, P2O5, H; at 140°C in sealed tube; NaH2PO2 : AgCl = 1:4;;
参考文献
Kolitowska, J. H.; Rudnicki, R.
Roczniki Chemii, 1969 , vol. 43, p. 1825 - 1829
Full Text Show Details
Gmelin Handbook: Ag: MVol.B4, 18.2.1, page 3 - 3
water in water
react. on boiling 5 percent AuCl3 soln.; react. of Au(3+) with H2PO2(1-) and H2O forming Au, H2PO3(1-) and H(1+); formation of H2 by resct. of H2PO2(1-) with water;;
参考文献
Sieverts, A.
Z. Anorg. Chem., 1909 , vol. 64, p. 29 - 64
Berlandt, L.
Archiv der Pharmazie (Weinheim, Germany), 1865 , vol. 172, p. 237 - 241
Full Text Show Details
Gmelin Handbook: Au: MVol.3, 7.2, page 660 - 662
water in not given
react. of a soln. of 5 ml 0.025 n NaH2PO2 and 25 ml 0.1 n NaICl4 at 60-70 °C;; 80.3 percent H3PO2 are oxidized after 1 h, 80.9 percent after 2 h and 99.9 percent after 42 h;;
参考文献
Fialkov, Ya. F.; Kagan, F. E.
Zh. obshchei Khim., 1954 , vol. 24, p. 3 - 10
Full Text Show Details
Gmelin Handbook: P: MVol.C, 53, page 112 - 113
in hydrogenchloride
react. of a soln. of NaH2PO2 and ICl in weakly acidic soln. (5 ml 0.1 n NaH2PO2 + 25 ml 0.1 n ICl in 0.4 n HCl) at ambient temp.;; 51.2 percent H3PO2 are oxidized after 0.5 h, 79.5 percent after 1 h, 97.9 percent after 3 h, 99.8 percent after 4 h;;
参考文献
Fialkov, Ya. F.; Kagan, F. E.
Zh. obshchei Khim., 1954 , vol. 24, p. 3 - 10
Full Text Show Details
Gmelin Handbook: P: MVol.C, 53, page 112 - 113
water in not given
react. of a soln. of 5 ml 0.025 n NaH2PO2 and 25 ml 0.1 n NaICl4 at 60-70 °C;; 80.3 percent H3PO2 are oxidized after 1 h, 80.9 percent after 2 h and 99.9 percent after 42 h;;
参考文献
Fialkov, Ya. F.; Kagan, F. E.
Zh. obshchei Khim., 1954 , vol. 24, p. 3 - 10
Full Text Show Details
Gmelin Handbook: P: MVol.C, 53, page 112 - 113
in hydrogenchloride
react. of a soln. of NaH2PO2 and ICl in weakly acidic soln. (5 ml 0.1 n NaH2PO2 + 25 ml 0.1 n ICl in 0.4 n HCl) at ambient temp.;; 51.2 percent H3PO2 are oxidized after 0.5 h, 79.5 percent after 1 h, 97.9 percent after 3 h, 99.8 percent after 4 h;;
参考文献
Fialkov, Ya. F.; Kagan, F. E.
Zh. obshchei Khim., 1954 , vol. 24, p. 3 - 10
Full Text Show Details
Gmelin Handbook: P: MVol.C, 53, page 112 - 113
