aluminium trichloride; carbon in neat (no solvent) byproducts: CO; chlorination at 800 K for 2 h, heating up to 1300 K in CO-HCl mixt., CVTalong temp. gradient at 1300 K for 6 h;
参考文献
Journal of Alloys and Compounds, , vol. 335, # 1-2 p. 196 - 199
hydrogenchloride in neat (no solvent) Kinetics; byproducts: H2O; sample fluidization in Pyrex glass in Ar/HCl gas mixt. at const. temp. in range 180-210 (+/-0.2)°C; manometric monotoring;
in neat (no solvent) absence of moisture; large excess AlCl3, evacuated quartz tube, 573 K; fractional sublimation over 450 to 650 K gradient, removal of residual AlCl3 on heating in Cl2/N2 stream;
in neat (no solvent) chemical transport technique, according to: G. N. Papatheodorou, G. H. Kucera, Inorg. Chem. 18 (1979) 385; AlCl3 prepd. in situ; 1 atm of Cl2, temp. gradient 500 to 400°C;
参考文献
Journal of Magnetism and Magnetic Materials, , vol. 69, p. 53 - 60
