byproducts: P, N2, CO; Heating (1000°C, 17 h, Ar or N2) intimately ground mixt. of starting materials in molar ratio NaCN:BPO4 between 1.714 and 2.; Removal of soluble compd. by washing a fraction of light-colored products with hot (80°C) H2O and then with acetone followed by drying of residues (120°C). XRD and EDX for solids, and Raman spectroscopy for solids and aliquots of aq. ext.;
参考文献
Bamberger; Begun
Journal of the American Ceramic Society, 1986 , vol. 69, # 5 p. c. 95-c. 97
byproducts: CO, P, N2; Heating (1000°C, 17 h, Ar or N2) intimately ground mixt. of starting materials in molar ratio NaCN:BPO4 between 1.24 and 1.714.; Removal of soluble compd. by washing a fraction of light-colored products with hot (80°C) H2O and then with acetone followed by drying of residues (120°C). XRD and EDX for solids, and Raman spectroscopy for solids and aliquots of aq. ext.;
参考文献
Journal of the American Ceramic Society, , vol. 69, # 5 p. c. 95-c. 97
sulfur in neat (no solvent) ignition of BN tablets and S on Ni-disk (bomb, P(F2) = 520 kPa); calorimetric measurements;
参考文献
Leonidovv, V. Ya.; Timofeev, I. V.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1989 , vol. 34, p. 1545 - 1546
Zhurnal Neorganicheskoi Khimii, 1989 , vol. 34, p. 2701 - 2704
