in methanol; water Kinetics; investigation of ligand substitution react. in 95/5 vol.percent CH3OH/H2O at 25°C;; not isolated; monitored by UV spectrophotometry;;
参考文献
Cattalini, Lucio; Chessa, Gavino; Michelon, Gianni; Pitteri, Bruno; Tobe, Martin L.; Zanardo, Andrea
Inorganic Chemistry, 1985 , vol. 24, p. 3409 - 3413
hydrogen cation in water Irradiation (UV/VIS); photolysis of oxygenated bromide solns. by UV- and visible light in presence of the Ir(III)-complex as photosensitizer, investigation of pH, illumination dose and O2- and Br(1-)-concn. on the quantum yield of Br3(1-); discussion of mechanism;; not isolated; analysis of Br3(1-) and H2O2 by reduction of KI and absorption measurements (350nm) of resulting I3(1-); measurement of emission spectra; identification of transients formed during react. by absorptionmeasurements;;
参考文献
Slama-Schwok, Anny; Gershuni, Shlomo; Rabani, Joseph; Cohen, Haim; Meyerstein, Dan
Journal of Physical Chemistry, 1985 , vol. 89, # 12 p. 2460 - 2464
