sulfuric acid in not given at room temp.; with dild. H2SO4 soln., CO2 flow; retardation effect in presence of alkali sulfates; activation effect with 2 and 3 valent metal sulfates except CdSO4 (retarding); strong activating by MnSO4;
Luther
Zeitschrift fuer Elektrochemie, 1907 , vol. 13, p. 437 - 437
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Gmelin Handbook: Cl: MVol., 122, page 324 - 326
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Rutter
Dissert. Leipzig 1906, S. 60
sodium perchlorate in water Kinetics; soln. of 2KHSO5*KHSO4*K2SO4 in H2O reacted with Br(1-) (excess) at pH 0.8 in presence of NaClO4 at 25°C; not isolated; monitored by UV-vis spectra;
oxygen in neat (no solvent) Kinetics; with group I and group II halogenides at 550°C, react.-rate depending on cation; increase of decompn.-rate in presence of H2O;;
anatase O2Ti in water Irradiation (UV/VIS); bubbled with oxygen in acidic or basic water; in the absence of TiO2 orof UV light no oxidation occured;
参考文献
Herrmann, Jean-Marie; Pichat, Pierre
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1980 , vol. 76, p. 1138 - 1146
hydrogen cation in perchloric acid; nitric acid Kinetics; byproducts: H2O; kinetic investigation of the autocatalytic react. at 25°C, pH 0.4-2.5, investigation of influemce of chlorite- and bromide-concn., discussion of mechanism;; not isolated, monitoring of react. by UV (390nm, production of Br2) andpotentiometric measurements;;
参考文献
Simoyi, Reuben H.
Journal of Physical Chemistry, 1985 , vol. 89, # 16 p. 3570 - 3574
