1,1-二甲氧基-2-苯基乙烷合成路线 （共 75 条）
反应条件
1.1: t-BuOK; BuLi / hexane; tetrahydrofuran / 2 h / -95 °C
1.2: ClSnBu3 / hexane; tetrahydrofuran / 2 h / -95 - -50 °C
1.3: 0.45 g / Pd(PPh3)4 / CHCl3 / 2 h / 60 °C
2.1: 74 percent / Amberlyst-15 / CH2Cl2 / 1 h / 25 °C
View Scheme
参考文献
Tivola, Paolo Balma; Deagostino, Anna; Prandi, Cristina; Venturello, Paolo
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 4 p. 437 - 441
反应条件
hydrogenchloride in diethyl ether; water
8 h;
参考文献
Uehlin, Lars; Wirth, Thomas
Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 6 p. 1374 - 1385
反应条件
1: (i) aq. H3PO4, Py, (ii) Br2, (iii) /BRN= 1098229/, NaOMe
2: (i) NaH, DMF, (ii) /BRN= 2615518/
View Scheme
参考文献
Schank,K.; Hachmann,H.
Justus Liebigs Annalen der Chemie, 1972 , vol. 760, p. 27 - 36
反应条件
(i) aq. H3PO4, Py, (ii) /BRN= 774156/, (iii) /BRN= 1098229/, NaOMe; Multistep reaction;
参考文献
Schank,K.; Hachmann,H.
Justus Liebigs Annalen der Chemie, 1972 , vol. 760, p. 27 - 36
反应条件
Na[B(3,5-(CF3)2C6H3)4] in water
T=30°C; 15 h;
参考文献
Chang, Chih-Ching; Liao, Bei-Sih; Liu, Shiuh-Tzung
Synlett, 2007 , # 2 p. 283 - 287
