4,4'-二氨基二苯甲烷合成路线 （共 194 条）
反应条件
Zn4O(OAc)6 T=180°C; 2.5 h; Inert atmosphereAutoclave;
参考文献
Bayer MaterialScience AG
Patent: EP2230228 A1, 2010 ;
Location in patent: Page/Page column 8 ;
参考文献
Murphy, William S.; Raman, Krishna P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 447 - 448
反应条件
2: tin; HCl / 135 - 140 °C 3: 80 - 135 °C View Scheme
参考文献
Benda
Chemische Berichte, 1912 , vol. 45, p. 1796
反应条件
hydrogenchloride Diazotization.Eingiessen der Diazoniumsalzloesung in Kaliumkupfercyanuerloesung;
参考文献
Schoepff
Chemische Berichte, 1894 , vol. 27, p. 2322
反应条件
in xylene at reflux 140-106°C for 27 h, then distilling butanol-borane azeotrop;
参考文献
Gmelin Handbook: B: B-Verb.1, 3.5.4.4, page 260 - 263
Full Text Show Details
U.S. Borax & Chemical Corp.
Patent: US3159590 , 1964 ;
C.A., 1965 , vol. 62, p. 11932
反应条件
in xylene at reflux 140-106°C for 32 h, then distilling butanol-borane azeotrop;
参考文献
Gmelin Handbook: B: B-Verb.1, 3.5.4.4, page 260 - 263
Full Text Show Details
U.S. Borax & Chemical Corp.
Patent: US3159590 , 1964 ;
C.A., 1965 , vol. 62, p. 11932
反应条件
sodium tetrahydroborate; sulfuric acid in tetrahydrofuran T=-10 - 20°C;
参考文献
Giuamanini, Angelo G.; Chiavari, Giuseppe; Musiani, Marco M.; Rossi, Patrizia
Synthesis, 1980 , # 9 p. 743 - 746
反应条件
lauryl dimethyl carboxymethyl betaine in ethylbenzene T=70°C; 8 h; Heating / refluxAzeotropic water removal; Product distribution / selectivity;
参考文献
VUCHT, a.s.
Patent: WO2007/64306 A1, 2007 ;
Location in patent: Page/Page column 5 ;
反应条件
1: toluene / 3 h / 20 °C 2: [BsMIm][HSO4] / 1-Propyl acetate / 3 h / Reflux View Scheme
参考文献
Li, Kai; Yuan, Chao; Zheng, Shijun; Fang, Qiang
Tetrahedron Letters, 2012 , vol. 53, # 32 p. 4245 - 4247
参考文献
Stein
Chemische Berichte, 1894 , vol. 27, p. 2806
