4,4'-二氨基二苯甲烷合成路线 （共 194 条）
反应条件
Basolite® A100
T=170°C; 8 h;
参考文献
Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Garcia, Hermenegildo
Applied Catalysis A: General, 2010 , vol. 378, # 1 p. 19 - 25
反应条件
1: With toluene-4-sulfonic acid in water
T=20°C;
2: With potassium iodide in water
T=20°C; 2 h;
参考文献
Trusova, Marina E.; Krasnokutskaya, Elena A.; Postnikov, Pavel S.; Choi, Younghwa; Chi, Ki-Whan; Filimonov, Victor D.
Synthesis, 2011 , # 13 p. 2154 - 2158
反应条件
hydrogen; 5 Ru/Al2O3 in tetrahydrofuran
T=83 - 105°C;
参考文献
DEGUSSA AG
Patent: WO2004/7425 A2, 2004 ;
Location in patent: Page 9-12 ;
反应条件
hydrogen; 5 Ru/Al2O3 in tetrahydrofuran
T=90 - 110°C;
参考文献
DEGUSSA AG
Patent: WO2004/7425 A2, 2004 ;
Location in patent: Page 9-12 ;
参考文献
Schneider, Hans-Joerg; Philippi, Klaus
Chemische Berichte, 1984 , vol. 117, # 10 p. 3056 - 3074
反应条件
Zn(CH3COO)2*2H2O
T=180°C; P=6000.6 Torr; 2.66667 h; AutoclaveInert atmosphere; Product distribution / selectivity;
参考文献
Bayer MaterialScience AG
Patent: EP2230228 A1, 2010 ;
Location in patent: Page/Page column 9; 10 ;
反应条件
oxygen; triphenylphosphine; AuCl(PPh3)2
T=200°C; P=37503.8 Torr; 3 h;
参考文献
Shi; Deng
Chemical Communications, 2001 , # 5 p. 443 - 444
反应条件
scandium tris(trifluoromethanesulfonate) in tetrahydrofuran
T=89.85°C; 24 h; Title compound not separated from byproducts;
参考文献
Distaso, Monica; Quaranta, Eugenio
Journal of Catalysis, 2004 , vol. 228, # 1 p. 36 - 42
反应条件
1: 1.2-dichloro-benzene
View Scheme
参考文献
Siefken
Justus Liebigs Annalen der Chemie, 1949 , vol. 562, p. 75,1114
反应条件
1: 93 percent / sulfuric acid, nitric acid / -40 °C
2: 1) sodium nitrite, sulfuric acid; 2) copper(I) oxide, ethanol / 1) acetic acid, 18 deg C, 1 h.; 2) 60 deg C, 80 min.
3: 52 percent / tin, conc. HCl / ethanol / 1 h / Heating
View Scheme
参考文献
McKinnon, David M.; Duncan, K. Ann
Journal of Heterocyclic Chemistry, 1988 , vol. 25, p. 1095 - 1098
