in neat (no solvent, gas phase)
accelerated and energy selected ion beam is injected into a collision cell holding the neutral reactant gas (ambient temp., 2 mTorr); products detected by mass spectrometry;
参考文献
Schilling, J. Bruce; Beauchamp, J. L.
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 15 - 24
in gaseous matrix
Kinetics; Irradiation (UV/VIS); laser photolysis at 193 nm mixt. of EtOCCH (partial pressure 0.01-0.02 Torr), NO (0-0.6 Torr), buffer gas SF6 (0-0.5 Torr) at 296 K; not separated; detected by IR;
参考文献
Meyer, Justin P.; Hershberger, John F.
Journal of Physical Chemistry B, 2005 , vol. 109, # 17 p. 8363 - 8366
byproducts: H2CO; Irradiation (UV/VIS); photolysis of CH2CO/NO/Ar mixt. with 200 W high pressure Hg lamp (photolysis of CH2CO generates CH2 radicals) in Duran glass tube (20 cm long, 4cm i.d.) at room temp. and ambient pressure;
参考文献
Grussdorf; Temps; Gg Wagner
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1997 , vol. 101, # 1 p. 134 - 138
Dobbie, R. C.
Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1971 , p. 2894 - 2897
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Gmelin Handbook: F: PerFHalOrg.3, 1.8, page 51 - 70
Dobbie, R. C.
Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1971 , p. 2894 - 2897
Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.8, page 51 - 70
Dobbie, R. C.
Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1971 , p. 2894 - 2897
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Gmelin Handbook: F: PerFHalOrg.3, 1.8, page 51 - 70
catalyst: Pt/γ-Al2O3; SO2 in neat (no solvent, gas phase)
byproducts: BaSO4; mixt. of NO and SO2 (44-:25) reacted with O2 in N2 at 350-500°C and 1 atm; detected by Raman spectra;
参考文献
Uy, Dairene; Wiegand, Kelly A.; O'Neill, Ann E.; Dearth, Mark A.; Weber, Willes H.
Journal of Physical Chemistry B, 2002 , vol. 106, # 2 p. 387 - 394
in not given
in neutral, 1.25 n Na2S2O3 soln., in absence of O2;
参考文献
Kurtenacker, A.; Loeschner, H.
Z. Anorg. Chem., 1938 , vol. 238, p. 335 - 349
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Gmelin Handbook: S: MVol.B2, 7.5.2, page 907 - 910
carbon
byproducts: CO, CO2, N2; investigation of reduction of NO on the C-covered Rh(331) surface at different temperatures >400K; discussion of mechanism;; not isolated, detected by XPS and SIMS;;
参考文献
DeLouise, L. A.; Winograd, N.
Surface Science, 1985 , vol. 154, p. 79 - 89
