H2; palladium in neat (no solvent)
Kinetics; byproducts: H2O; react. of Pd-adsorbed NO and H2 between 300 and 900 K; not isolated, detected by flash desorption and U-PES;
catalyst:colodial Pt/Al2O3 in gas
byproducts: N2O, N2; 350-600 °C, quartz reactor, 1percent of colloidal Pt/Al2O3 as catalyst;0.41percent CH4, 1percent NO and Ar in gas mixt., gas space velocity 60000 h**-1, t otal flow rate 50 cm**3 min**-1; yield depends on temp. and Pt morphology;
参考文献
Balint, Ioan; Miyazaki, Akane; Aika, Ken-Ichi
Chemical Communications, 2002 , # 10 p. 1044 - 1045
CO in gaseous matrix
react. carried out at 573 K by use of conventional flow system with fixed bed of catalyst (Pt-Al2O3) under gas composition NO, CO 3percent, H2O 1.7percent,He 92.3percent for 150 min; gas chromy. and MS anal.;
参考文献
Nakamura; Nakai; Sugiyama; Echigoya
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 7 p. 1950 - 1953
catalyst: Ag/Al2O3; O2; ethanol in neat (no solvent, gas phase)
byproducts: NCO, C2H4, CH3CHO; selective catalytic reduction at different temperatures; monitored by FTIR and mass spectrometry;
参考文献
Bion, Nicolas; Saussey, Jacques; Haneda, Masaaki; Daturi, Marco
Journal of Catalysis, 2003 , vol. 217, # 1 p. 47 - 58
catalyst: H-FER-17, H-FER-64, or Na-ferrierite in gas
Kinetics; over H-FER-17, H-FER-64 or Na-ferrierite; investigated in the range 200-500 °C; only traces of NH3 formed at 500 °C;
参考文献
Nanba; Obuchi; Sugiura; Kouno; Uchisawa; Kushiyama
Journal of Catalysis, 2002 , vol. 211, # 1 p. 53 - 63
