water in gas Irradiation (UV/VIS); react. gas (NO/NO2-N2 mixt.) and O2 passed through cylinder coated with carbon or TiO2-carbon or TiO2-carbon-Fe2O3 as catalyst at different humidity for 5-10 h at ca. 310 K, photoillumination (300-400 nm); inner glass cylinder removed from react. system, immersed into water; HNO3 determined by ion chromy.;
参考文献
Ibusuki; Takeuchi
Journal of molecular catalysis, 1994 , vol. 88, # 1 p. 93 - 102
in gas Kinetics; Irradiation (UV/VIS); at room temp. and pressure 30-700 Torr; PLP-PLIF;
参考文献
Burrows, John P.; Wallington, Timothy J.; Wayne, Richard P.
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1983 , vol. 79, p. 111 - 122
in gaseous matrix Kinetics; byproducts: NO, H2O, H2O2; discharge flow technique, pressure: 3 - 850 Torr, temp.: 248 - 298 K, He, N2 or SF6 as carrier gas; monitoring by IR spectroscopy; < 5percent formation of HOONO, 65-100percent HONO2;;
参考文献
Donahue, Neil M.; Mohrschladt, Ralf; Dransfield, Timothy J.; Anderson, James G.; Dubey, Manvendra K.
Journal of Physical Chemistry A, 2001 , vol. 105, # 9 p. 1515 - 1520
