in gaseous matrix Irradiation (UV/VIS); photolysis using 172 nm Xe2 excimer lamp in air for 1.5 min at a total pressure of 1 atm at room temp.; gas analysis by FTIR and quadruple mass spectrometer;
in neat (no solvent) Kinetics; generation NH2-radicals by infrared multiple-photon dissociation of N2H4, NH3 and CH3NH2; not isolated; investigation of reaction by the sensitive laser-induced fluorescene (LIF) technique;;
参考文献
Xiang, Tian-Xiang; Torres, Lourdes M.; Guillory, William A.
Journal of Chemical Physics, 1985 , vol. 83, # 4 p. 1623 - 1629
water in gaseous matrix Kinetics; byproducts: N2O4; investigation in a fast flow react. system facility; mixing NO2/N2 with O3 and zero grade air; introduction of gas mixt. of NO3, N2O5, NO2, O3, N2 and zero grade air into react. vessel; introduction of SO2 and H2O vapor (1 atm, 26.5+/-1°C); detn. of condensation nuclei concn.;
参考文献
Xie, Zhilong Diane
Journal of Physical Chemistry, 1992 , vol. 96, # 4 p. 1543 - 1547
