NaNO2/NaNO3/KNO3 eutectic melt in melt
byproducts: Cl(1-), NO3(1-), NO; sample heating in NaNO2/NaNOP3/KNO3 eutectic melt in Pyrex tube under air atmosphere at 2 K/min up to 600°C; solid washing, drying; TG;
methanol in solid matrix
Kinetics; other Radiation; 77°C; solvent - CH3OH; γ-irradn.; EPR;
参考文献
Ershov, V. G.; Gaponova, I. S.
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), 1981 , vol. 259, p. 627 - 629
Doklady Akademii Nauk SSSR, 1981 , vol. 261, p. 391 - 394
in neat (no solvent)
decompn.; mechanism discussed;;
参考文献
Clyne, M. A. A.; Coxon, J. A.
Transactions of the Faraday Society, 1966 , vol. 62, p. 1175 - 1189
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Coxon, J. A.
Transactions of the Faraday Society, 1968 , vol. 64, p. 2118 - 2123
Knox, J.; Reid, D. M.
J. Soc. Chem. Ind., London, Trans. Commun., 1919 , vol. 38, p. 105
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Gmelin Handbook: N: MVol.4, 6.5, page 915 - 929
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反应条件
in nitric acid
byproducts: Cl2; to Ru complex was added concd. HNO3; mixt. heated under reflux for 5 min; cooled to room temp.; ppt. filtered off; washed (water, alc., ether); dried (vac.); recrystd. (aq. HNO3); elem. anal.;
