N-2-(溴苯基)甲酰胺合成路线 （共 38 条）
反应条件
Yield given. Multistep reaction;
参考文献
Curran, Dennis P.; Kuo, Shen-Chun
Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2063 - 2065
反应条件
1: n-butyl lithium / hexane; tetrahydrofuran / -100 °C
2: 56 percent / tetrahydrofuran / -105 °C
3: 80 percent / dimethylformamide / 80 °C
View Scheme
参考文献
Fleming, Ian; Loreto, Maria Antonietta; Wallace, Ian H.M.; Michael, Joseph P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 349 - 360
反应条件
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / water; toluene; ethanol / 24 h / |Reflux; |Inert atmosphere
2: tri-ruthenium(0)dodecacarbonyl / chlorobenzene; N,N-dimethyl acetamide / 20 - 120 °C / |Sealed tube
View Scheme
参考文献
Li, Bin; Park, Yoonsu; Chang, Sukbok
Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 1125 - 1131
反应条件
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / water; toluene; ethanol / 24 h / |Reflux; |Inert atmosphere
2: tri-ruthenium(0)dodecacarbonyl; tetra-(n-butyl)ammonium iodide / toluene; dimethyl sulfoxide / 20.08 h / 20 - 120 °C / |Sealed tube
View Scheme
参考文献
Li, Bin; Park, Yoonsu; Chang, Sukbok
Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 1125 - 1131
反应条件
1: n-butyl lithium / hexane; tetrahydrofuran / -100 °C
2: 56 percent / tetrahydrofuran / -105 °C
3: 8 percent / dimethylformamide / 80 °C
4: 87 percent / HCl / H2O / 144 h / 165 °C
View Scheme
参考文献
Fleming, Ian; Loreto, Maria Antonietta; Wallace, Ian H.M.; Michael, Joseph P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 349 - 360
反应条件
1: n-butyl lithium / hexane; tetrahydrofuran / -100 °C
2: 56 percent / tetrahydrofuran / -105 °C
3: 88 percent / dimethylformamide / 80 °C
View Scheme
参考文献
Fleming, Ian; Loreto, Maria Antonietta; Wallace, Ian H.M.; Michael, Joseph P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 349 - 360
反应条件
1.1: 85 °C
2.1: potassium hexamethylsilazane / toluene; tetrahydrofuran / 1.5 h / -78 °C
2.2: -78 °C
View Scheme
参考文献
STATE OF OREGON ACTING BY and THROUGH THE ST. BOARD OF HIGHER EDUCATION ON BEHALF OF THE UNIVERSITY OF OREGON; UNIVERSITY DISPLAY CORPORATION; LIU, Shih-Yuan; XU, Senmiao; KWONG, Raymond, C.
Patent: WO2014/4985 A1, 2014 ;
反应条件
2: TiCl4 / CH2Cl2 / 1.5 h / -78 °C
3: 61 percent / polyphosphoric acid / 130 °C
View Scheme
参考文献
Curran, Dennis P.; Kuo, Shen-Chun
Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2063 - 2065
