2,3,4,5,6-五氯苯甲酸合成路线 （共 28 条）
反应条件
(2,2'-bipyridine-N,N')dichloronickel; zinc in water; N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Trukhin; Adonin; Starichenko
Russian Journal of Organic Chemistry, 2002 , vol. 38, # 6 p. 900 - 901
反应条件
thionyl chloride 48 h; Heating;
参考文献
Ruberu, Shiyamalie; Fox, Marye Anne
Journal of Physical Chemistry, 1993 , vol. 97, # 1 p. 143 - 149
反应条件
sulfuric acid
T=100°C; 1 h;
参考文献
Ballester, Manuel; Castaner, Juan; Riera, Juan; Tabernero, Ignacio
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1413 - 1419
反应条件
tetrabutylammomium bromide in N,N-dimethyl-formamide
T=-5 - 0°C; Dehalogenation; Carboxylation; Electrochemical reaction; Further byproducts given;
参考文献
Golinske, Dirk; Voss, Juergen; Adiwidjaja, Gunadi
Collection of Czechoslovak Chemical Communications, 2000 , vol. 65, # 6 p. 862 - 880
反应条件
1: 85 percent / Zn / dioxane / 16 h / Heating
2: 1.) AgNO3, 2.) Cl2 / 1.) H2O, THF, 30 min, 2.) CCl4, 5 min
3: 52 percent / concd. H2SO4 / 1 h / 100 °C
4: 85 percent / 20percent oleum / 1 h / 100 °C
View Scheme
参考文献
Ballester, Manuel; Castaner, Juan; Riera, Juan; Tabernero, Ignacio
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1413 - 1419
反应条件
1: 1.) AgNO3, 2.) Cl2 / 1.) H2O, THF, 30 min, 2.) CCl4, 5 min
2: 52 percent / concd. H2SO4 / 1 h / 100 °C
3: 85 percent / 20percent oleum / 1 h / 100 °C
View Scheme
参考文献
Ballester, Manuel; Castaner, Juan; Riera, Juan; Tabernero, Ignacio
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1413 - 1419
反应条件
sulfuric acid
T=100°C; 1 h;
参考文献
Ballester, Manuel; Castaner, Juan; Riera, Juan; Tabernero, Ignacio
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1413 - 1419
反应条件
potassium permanganate; water; sodium carbonate
参考文献
Lock
Chemische Berichte, 1939 , vol. 72, p. 300,304
Full Text Show Details
Ross
Journal of the American Chemical Society, 1948 , vol. 70, p. 4039,4041
反应条件
diethyl ether; magnesium
Eintragen einer Loesung von 1.2-Dibrom-aethan in Benzol und Einleiten von Kohlendioxid in das Reaktionsgemisch;
参考文献
Pearson; Cowan
Organic Syntheses, 1964 , vol. 44, p. 78
Full Text Show Details
Pearson et al.
Journal of Organic Chemistry, 1959 , vol. 24, p. 504,508
反应条件
hydrogenchloride; manganese(IV) oxide
T=180 - 200°C;
参考文献
Claus; Buecher
Chemische Berichte, 1887 , vol. 20, p. 1621
