bis-triphenylphosphine-palladium(II) chloride; triethylamine P=114000 Torr; 94 h; Ambient temperature;

dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide T=25°C; 0.1 h;

dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide T=25°C; 0.1 h;

bis-triphenylphosphine-palladium(II) chloride; triethylamine P=114000 Torr; 94 h; Ambient temperature;

Cu(xantphos)I; caesium carbonate in 1,4-dioxane T=135°C; Inert atmosphere;

in acetonitrile T=20°C; 6 h; UV-irradiationInert atmosphereVycor filter;

tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenyl-arsane; [Ph2PO2]1-*[NBu4]1+ in 1-methyl-pyrrolidin-2-one T=45°C; Stille coupling; 3 h; Inert atmosphere;

potassium carbonate; dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) in tetrahydrofuran; N,N-dimethyl-formamide To a soln. of 9-octyl-9-BBN is added (C6H5)(CH2)2I, THF-DMF and pwd. K2CO3, mixt. is stirred for 8 h at 50°C, poured into water.; Extracted with benzene, washed with water, dried (MgSO4), final product E/Z=99/1.;

sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 1.) THF, r.t., 6 h; 2.) THF, 65 deg C, 16 h; Yield given. Multistep reaction. Yields of byproduct given;