甲基4-羟基-3-(3-甲基丁-2-烯基)苯甲酸酯合成路线 (共 5 条)
反应条件
1: 100 percent / hydrogen / Lindlar's catalyst / hexane / 3 h / 25 °C 2: 72 percent / N,N-dimethyl-aniline / 1 h / 195 °C View Scheme
参考文献
Nicolaou; Pfefferkorn; Roecker; Cao; Barluenga; Mitchell
Journal of the American Chemical Society, 2000 , vol. 122, # 41 p. 9939 - 9953
反应条件
1: 71 percent / potassium carbonate; potassium iodide; copper (I) iodide / dimethylformamide / 2 h / 25 - 65 °C 2: 100 percent / hydrogen / Lindlar's catalyst / hexane / 3 h / 25 °C 3: 72 percent / N,N-dimethyl-aniline / 1 h / 195 °C View Scheme
参考文献
Nicolaou; Pfefferkorn; Roecker; Cao; Barluenga; Mitchell
Journal of the American Chemical Society, 2000 , vol. 122, # 41 p. 9939 - 9953
反应条件
potassium hydroxide in 1,4-dioxane; methanol
参考文献
Zdero, C.; Bohlmann, F.; Anderberg, A.
Phytochemistry (Elsevier), 1991 , vol. 30, # 8 p. 2703 - 2706
反应条件
1: With polystyrene-based selenenyl bromide resin in dichloromethane T=0 - 25°C; 0.333333 h; 2: With dihydrogen peroxide in tetrahydrofuran T=25°C; 0.333333 h; Further stages.;
参考文献
Nicolaou; Pfefferkorn; Roecker; Cao; Barluenga; Mitchell
Journal of the American Chemical Society, 2000 , vol. 122, # 41 p. 9939 - 9953
反应条件
pyridine; palladium (II) trifluoroacetate; oxygen; sodium carbonate in toluene T=80°C; 16 h; Molecular sieve;
参考文献
Worayuthakarn, Rattana; Boonya-Udtayan, Sasiwadee; Ruchirawat, Somsak; Thasana, Nopporn
European Journal of Organic Chemistry, 2014 , vol. 2014, # 12 p. 2496 - 2507