2-[(2-甲基苯氧基)甲基]环氧乙烷合成路线 （共 8 条）
反应条件
water in dichloromethane; acetonitrile
T=0 - 20°C; 48 h; Resolution of racemate;
参考文献
Zhu, Chengfeng; Yuan, Guozan; Chen, Xu; Yang, Zhiwei; Cui, Yong
Journal of the American Chemical Society, 2012 , vol. 134, # 19 p. 8058 - 8061
反应条件
triphenylphosphine; diethylazodicarboxylate in benzene
T=80°C; 12 h;
参考文献
Bisi, Alessandra; Rampa, Angela; Budriesi, Roberta; Gobbi, Silvia; Belluti, Federica; Ioan, Pierfranco; Valoti, Ermanno; Chiarini, Alberto; Valenti, Piero
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 7 p. 1353 - 1361
反应条件
water; chiral Co(III) salen-based in tetrahydrofuran
参考文献
Bredikhin; Strunskaya; Novikova; Azancheev; Sharafutdinova; Bredikhina
Russian Chemical Bulletin, 2004 , vol. 53, # 1 p. 213 - 218
反应条件
Jacobsen's (R,R)-(salen)Co(III) catalyst; 1-n-butyl-3-methylimidazolium hexafluorophosphate; 4-nitro-benzoic acid
T=20°C; 7 h; optical yield given as percent eeenantioselective reaction;
参考文献
Kureshy, Rukhsana I.; Prathap, K. Jeya; Agrawal, Santosh; Kumar, Manish; Khan, Noor-Ul H.; Abdi, Sayed H. R.; Bajaj, Hari C.
European Journal of Organic Chemistry, 2009 , # 17 p. 2863 - 2871
反应条件
Jacobsen's (R,R)-(salen)Co(III) catalyst; 1-n-butyl-3-methylimidazolium hexafluorophosphate; 4-nitro-benzoic acid
T=20°C; 7 h; optical yield given as percent eeenantioselective reaction;
参考文献
Kureshy, Rukhsana I.; Prathap, K. Jeya; Agrawal, Santosh; Kumar, Manish; Khan, Noor-Ul H.; Abdi, Sayed H. R.; Bajaj, Hari C.
European Journal of Organic Chemistry, 2009 , # 17 p. 2863 - 2871
反应条件
Jacobsen's (R,R)-(salen)Co(III) catalyst; 1-n-butyl-3-methylimidazolium hexafluorophosphate; 4-nitro-benzoic acid
T=20°C; 7 h; optical yield given as percent eeenantioselective reaction;
参考文献
Kureshy, Rukhsana I.; Prathap, K. Jeya; Agrawal, Santosh; Kumar, Manish; Khan, Noor-Ul H.; Abdi, Sayed H. R.; Bajaj, Hari C.
European Journal of Organic Chemistry, 2009 , # 17 p. 2863 - 2871
反应条件
1: 52 percent / PPH3; DEAD / tetrahydrofuran / 12 h / 0 °C
2: 76 percent / 10 percent HCl / 3 h / 80 °C
3: 1.5 g / PPh3; DEAD / benzene / 12 h / 80 °C
View Scheme
参考文献
Bisi, Alessandra; Rampa, Angela; Budriesi, Roberta; Gobbi, Silvia; Belluti, Federica; Ioan, Pierfranco; Valoti, Ermanno; Chiarini, Alberto; Valenti, Piero
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 7 p. 1353 - 1361
反应条件
1: 76 percent / 10 percent HCl / 3 h / 80 °C
2: 1.5 g / PPh3; DEAD / benzene / 12 h / 80 °C
View Scheme
参考文献
Bisi, Alessandra; Rampa, Angela; Budriesi, Roberta; Gobbi, Silvia; Belluti, Federica; Ioan, Pierfranco; Valoti, Ermanno; Chiarini, Alberto; Valenti, Piero
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 7 p. 1353 - 1361
